615 research outputs found
Free Radicals in Superfluid Liquid Helium Nanodroplets: A Pyrolysis Source for the Production of Propargyl Radical
An effusive pyrolysis source is described for generating a continuous beam of
radicals under conditions appropriate for the helium droplet pick-up method.
Rotationally resolved spectra are reported for the vibrational mode of
the propargyl radical in helium droplets at 3322.15 cm. Stark spectra
are also recorded that allow for the first experimental determination of the
permanent electric dipole moment of propargyl, namely -0.150 D and -0.148 D for
ground and excited state, respectively, in good agreement with previously
reported ab initio results of -0.14 D [1]. The infrared spectrum of the
mode of propargyl-bromide is also reported. The future application of these
methods for the production of novel radical clusters is discussed
Numerical Rule-Learning in Ring-Tailed Lemurs (Lemur Catta)
We investigated numerical discrimination and numerical rule-learning in ring-tailed lemurs (Lemur catta). Two ring-tailed lemurs were trained to respond to two visual arrays, each of which contained between one and four elements, in numerically ascending order. In Experiment 1, lemurs were trained with 36 exemplars of each of the numerosities 1–4 and then showed positive transfer to trial-unique novel exemplars of the values 1–4. In Experiments 2A and 2B, lemurs were tested on their ability to transfer an ascending numerical rule from the values 1–4 to novel values 5–9. Both lemurs successfully ordered the novel values with above chance accuracy. Accuracy was modulated by the ratio between the two numerical values suggesting that lemurs accessed the approximate number system when performing the task
A structured approach to cope with impurities during industrial crystallization development
The perfect separation with optimal productivity, yield, and purity is very difficult to achieve. Despite its high selectivity, in crystallization unwanted impurities routinely contaminate a crystallization product. Awareness of the mechanism by which the impurity incorporates is key to understanding how to achieve crystals of higher purity. Here, we present a general workflow which can rapidly identify the mechanism of impurity incorporation responsible for poor impurity rejection during a crystallization. A series of four general experiments using standard laboratory instrumentation is required for successful discrimination between incorporation mechanisms. The workflow is demonstrated using four examples of active pharmaceutical ingredients contaminated with structurally related organic impurities. Application of this workflow allows a targeted problem-solving approach to the management of impurities during industrial crystallization development, while also decreasing resources expended on process development
A high-resolution infrared spectroscopic investigation of the halogen atom-HCN entrance channel complexes solvated in superfluid helium droplets
Rotationally resolved infrared spectra are reported for the X-HCN (X = Cl,
Br, I) binary complexes solvated in helium nanodroplets. These results are
directly compared with that obtained previously for the corresponding X-HF
complexes [J. M. Merritt, J. K\"upper, and R. E. Miller, PCCP, 7, 67 (2005)].
For bromine and iodine atoms complexed with HCN, two linear structures are
observed and assigned to the and ground
electronic states of the nitrogen and hydrogen bound geometries, respectively.
Experiments for HCN + chlorine atoms give rise to only a single band which is
attributed to the nitrogen bound isomer. That the hydrogen bound isomer is not
stabilized is rationalized in terms of a lowering of the isomerization barrier
by spin-orbit coupling. Theoretical calculations with and without spin-orbit
coupling have also been performed and are compared with our experimental
results. The possibility of stabilizing high-energy structures containing
multiple radicals is discussed, motivated by preliminary spectroscopic evidence
for the di-radical Br-HCCCN-Br complex. Spectra for the corresponding molecular
halogen HCN-X complexes are also presented.Comment: 20 pages, 15 figures, 6 tables, RevTe
Spectroscopy of free radicals and radical containing entrance-channel complexes in superfluid helium nano-droplets
The spectroscopy of free radicals and radical containing entrance-channel
complexes embedded in superfluid helium nano-droplets is reviewed. The
collection of dopants inside individual droplets in the beam represents a
micro-canonical ensemble, and as such each droplet may be considered an
isolated cryo-reactor. The unique properties of the droplets, namely their low
temperature (0.4 K) and fast cooling rates ( K s) provides
novel opportunities for the formation and high-resolution studies of molecular
complexes containing one or more free radicals. The production methods of
radicals are discussed in light of their applicability for embedding the
radicals in helium droplets. The spectroscopic studies performed to date on
molecular radicals and on entrance / exit-channel complexes of radicals with
stable molecules are detailed. The observed complexes provide new information
on the potential energy surfaces of several fundamental chemical reactions and
on the intermolecular interactions present in open-shell systems. Prospects of
further experiments of radicals embedded in helium droplets are discussed,
especially the possibilities to prepare and study high-energy structures and
their controlled manipulation, as well as the possibility of fundamental
physics experiments.Comment: 25 pages, 12 figures, 4 tables (RevTeX
Halo orbits in cosmological disk galaxies : tracers of information history
We analyze the orbits of stars and dark matter particles in the halo of a disk galaxy formed in a cosmological hydrodynamical simulation. The halo is oblate within the inner ∼20 kpc and triaxial beyond this radius. About 43% of orbits are short axis tubes—the rest belong to orbit families that characterize triaxial potentials (boxes, long-axis tubes and chaotic orbits), but their shapes are close to axisymmetric. We find no evidence that the self-consistent distribution function of the nearly oblate inner halo is comprised primarily of axisymmetric short-axis tube orbits. Orbits of all families and both types of particles are highly eccentric, with mean eccentricity �0.6. We find that randomly selected samples of halo stars show no substructure in “integrals of motion” space. However, individual accretion events can clearly be identified in plots of metallicity versus formation time. Dynamically young tidal debris is found primarily on a single type of orbit. However, stars associated with older satellites become chaotically mixed during the formation process (possibly due to scattering by the central bulge and disk, and baryonic processes), and appear on all four types of orbits. We find that the tidal debris in cosmological hydrodynamical simulations experiences significantly more chaotic evolution than in collisionless simulations, making it much harder to identify individual progenitors using phase space coordinates alone. However, by combining information on stellar ages and chemical abundances with the orbital properties of halo stars in the underlying self-consistent potential, the identification of progenitors is likely to be possible
Entrance Channel X-HF (X=Cl, Br, and I) Complexes studied by High-Resolution Infrared Laser Spectroscopy in Helium Nanodroplets
Rotationally resolved infrared spectra are reported for halogen atom - HF
free radical complexes formed in helium nanodroplets. An effusive pyrolysis
source is used to dope helium droplets with Cl, Br and I atoms, formed by
thermal dissociation of Cl, Br and I. A single hydrogen fluoride
molecule is then added to the droplets, resulting in the formation of the X-HF
complexes of interest. Analysis of the resulting spectra confirms that the
observed species have ground electronic states, consistent with
the linear hydrogen bound structures predicted from theory. Stark spectra are
also reported for these species, from which the permanent electric dipole
moments are determined.Comment: 41 pages, 16 figures, 5 table
WFPC2 Observations of Compact Star Cluster Nuclei in Low Luminosity Spiral Galaxies
We have used the Wide Field Planetary Camera 2 aboard the Hubble Space
Telescope to image the compact star cluster nuclei of the nearby, late-type,
low-luminosity spiral galaxies NGC 4395, NGC 4242, and ESO 359-029. We also
analyze archival WFPC2 observations of the compact star cluster nucleus of M33.
A comparative analysis of the structural and photometric properties of these
four nuclei is presented. All of the nuclei are very compact, with luminosity
densities increasing at small radii to the resolution limit of our data. NGC
4395 contains a Seyfert 1 nucleus with a distinct bipolar structure and bright
associated filaments which are likely due to [OIII] emission. The M33 nucleus
has a complex structure, with elongated isophotes and possible signatures of
weak activity, including a jet-like component. The other two nuclei are not
known to be active, but share similar physical size scales and luminosities to
the M33 and NGC 4395 nuclei. The circumnuclear environments of all four of our
program galaxies are extremely diffuse, have only low-to-moderate star
formation, and appear to be devoid of large quantities of dust. The central
gravitational potentials of the galaxies are also quite shallow, making the
origin of these types of `naked' nuclei problematic.Comment: to appear in the July 1999 Astronomical Journal; 38 pages (Latex), 5
tables (postscript), 21 figures (gif); postscript versions of the figures may
be obtained via anonymous ftp at
ftp://ftp.cv.nrao.edu/NRAO-staff/lmatthew/lanl-nucle
The Restyled Federal Rules of Evidence
A lightly edited transcript of the Symposium held at the William & Mary School of Law on October 28, 2011
The Restyled Federal Rules of Evidence
A lightly edited transcript of the Symposium held at the William & Mary School of Law on October 28, 2011
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